Kierownik:

 

dr hab. Tadeusz Krogulec, prof. UwB
e-mail: krogulec@uwb.edu.pl
tel. 085-745-78-03


Pracownicy:

Tematyka prac badawczych:

Kinetyka i mechanizm złożonych procesów elektrodowych, elektrochemia fullerenów, detektory elektrochemiczne w elektroforezie kapilarnej i wstrzykowej analizie przepływowej.

Przykładowy zakres prac magisterskich realizowanych w Zakładzie:

2005/2006

1. Chronopotencjometryczna detekcja cukrów i aminokwasów w elektroforezie kapilarnej
2. Badanie procesu utleniania kompleksów [IrX₂(CO)₂]^- (X = Cl, Br)
3. Badanie warunków trwałości polimeru C₆₀/Pd
4. Optymalizacja warunków tworzenia nanoporowatego tlenku glinu
5. Badanie wpływu modyfikacji powierzchni nanocząstek ferrytów na ich właściwości magnetyczne

2004/2005

1. Badanie rozkładu potencjału na końcu kapilar stosowanych w elektroforezie kapilarnej
2. Charakterystyka "gorących" mikroelektrod złotych i platynowych w wybranych elektrolitach
3. Badanie procesów elektrodowych glukozy w NaOH na mikroelektrodzie platynowej
4. Otrzymywanie i właściwości elektrochemiczne dwuwarstw składających się z polimerów C₆₀ fulleren/Pd oraz 2'-ferrocenylpirolidyno [3',4';1,2] C₆₀ fulleren/Pd
5. Badanie możliwości tworzenia monowymiarowych kryształów mieszanych w procesie utleniania (AsPh₄)[IrX₂(CO)₂] i [IrCl(p-toluidyna)(CO)₂] (X = Cl, Br)
6. Badanie właściwości magnetycznych nanocząsteczkowego magnetytu domieszkowanego kobaltem, niklem i manganem
7. Analiza nanoproszkowego magnetytu metodą spektroskopii Mössbauerowskiej

2003/2004

1. Próby zastosowania "gorących" mikroelektrod złotych i platynowych jako detektorów we wstrzykowej analizie przepływowej
2. Elektrochemiczna charakterystyka wydzielania wodoru i tlenu na mikroelektrodach złotej i platynowej w roztworach alkalicznych
3. Nowoczesna pracownia elektroanalizy
4. Utlenianie płaskokwadratowych kompleksów [IrX₂(CO)₂]^- (X = Cl, Br, I) w warunkach elektrochemicznych. Tworzenie 1-D kryształów molekularnych
5. Optymalizacja warunków syntezy nanocząsteczkowych tlenków żelaza

2002/2003

1. Zastosowanie mikroelektrody platynowej w elektrochemicznej detekcji wybranych węglowodanów we wstrzykowej analizie przepływowej i elektroforezie kapilarnej
2. Zastosowanie ultramikroelektrody platynowej w elektroforetycznym oznaczaniu wybranych flawonoidów
3. Polimery C₆₀/M z udziałem kompleksów irydu, rodu, platyny i palladu
4. Sonoelektrochemiczne badanie procesów polimeryzacji pirolu i właściwości tworzącego się polimeru

Publikacje:

2006

1. A. Basa, J. Magnuszewska, T. Krogulec and A.S. Baranski, Cyclic chronopotentiometric determination of sugars at Au and Pt microelectrodes in flowing solutions, J. Chromatogr. A, (2006), doi: 10.1016/j.chroma.2006.08.076.
2. A. Basa, J. Magnuszewska, T. Krogulec and A.S. Baranski, Cyclic chronopotentiometry as a detection tool for flowing solution systems, Anal. Chem., 78 (2006) 6747-6755.
3. M. Plonska, K. Winkler, S. Gadde, F. D'Souza, A.L. Balch, Redox active two-component films of palladium and covalently linked zinc porphyrin-fullerene dyad. Electroanalysis, 18 (2006) 841-848.
4. T. Krogulec, A. Basa, J. Magnuszewska, P. Kukla, A.S. Baranski, Sposób detekcji elektrochemicznej w elektroforezie kapilarnej, wniosek patentowy zgłoszony do Urzędu Patentowego RP - zarejestrowany pod numerem P 379393.
5. K. Winkler, M.E. Płońska, K. Rećko, L. Dobrzyński, Remarkable solvent effect on the structure and electrochemical properties of [(M(bipirydyl)₃](ClO₄)₃ (M = Co, Fe and Ru) films, Electrochim. Acta, 51 (2006) 4544-4553.

2005

1. E.P. Krinichnaya, A.P. Moravsky, O. Efimov, J.W. Sobczak, K. Winkler, W. Kutner, A.L. Balch, Mechanistic studies of the electrochemical polymerization of C₆₀ in the presence of dioxygen or C₆₀O, J. Mater. Chem., 15 (2005) 1468-1476.
2. E. Grodzka, K. Winkler, Conductivity and capacitance study of two-component films of fullerene C₆₀ and palladium, Annals of the Polish Chemical Society. Preliminary Reports Presented During Annual Meeting of the Polish Chemical Society. Poznań, September 18-22, 2005, W.W. Sułkowski (ed.) Polish Chemical Society, Warsaw, 2005, 359-364.

2004

1. M. Wysocka, K. Winkler, J. R. Stork, A. L. Balch, Electrochemical oxidation of (Ph₄As)[IrCl₂(CO)₂] in the presence of tetra(alkyl)ammonium salts. Electro-crystalization of different forms of iridium-based linear chain complexes, Chem. Mater., 16 (2004) 771-780.
2. A. Basa, T. Krogulec and A.S. Baranski, Multi-scan voltammetric determination of carbohydrates at noble metal microelectrodes following flow injection and after capillary electrophoresis separation, Pol. J. Chem., 78 (2004) 1635-1654.
3. M. Wysocka, K. Winkler, A.L. Balch, The electrochemical formation and properties of Bilayer composed of polypyrrole and C₆₀Pd films, J. Mater. Chem., 14 (2004) 1036-1042.
4. M. Wysocka, J. R. Stork, K. Winkler, A. L. Balch, Electrochemical oxidation of (Ph₄As)[IrCl₂(CO)₂] in the presence of tetra(alkyl)ammonium salts. Electrocrystalization of iridium-based linear chain complexes, Annals of the Polish Chemical Society. Preliminary Reports Presented During Annual Meeting of the Polish Chemical Society. Lublin, September 15-18, 2003, W.W. Sułkowski (ed.) Polish Chemical Society, Warsaw, 2003, 1020-1024.
5. M.E. Płońska, A. Makar, K. Winkler, A.L. Balch, Electrochemical formation of two-component films from 2'-ferrocenylpyrrolidino[3',4';1,2] [C₆₀]fullerene and transition metal complexes, Pol. J. Chem., 78 (2004) 1431-1447.
6. M. Plonska, K. Winkler, S. Gadde, F. D'Souza, A.L. Balch, Electrochemical formation of two-component electroactive films of palladium and fullerene covalently attached to a zinc porphyrin redox probe, Fullerenes and Nanotubes: Materials for the New Chemical Frontier, Vol. 14, D.M. Guldi., P.V. Kamat F.D'Souza (eds.), The Electrochemical Society, Inc., Pennington 2004, 30-38.
7. J. Magnuszewska, A. Baszun, Rozdział wybranych flawonoidów metodą elektroforezy kapilarnej z detekcją elektrochemiczną na mikroelektrodzie platynowej i złotej, Flawonoidy i ich zastosowanie, Oficyna Wydawnicza Politechniki Rzeszowskiej, 2004, 71-81.

2003

1. K. Winkler, M.E. Płońska, A. Basa, M. Lach, A.L. Balch, Mediated electrocatalysis at the electrodes covered with [M^III(bpy)₃](ClO₄)₃ (M = Co and Fe) in the presence of electroactive solutes, Electroanalysis, 15 (2003) 55-64.
2. K. Winkler, K. Noworyta, A. de Bettencourt-Dias, J.W. Sobczak, C.-T. Wu, L.-C.Chen, W. Kutner, A.L. Balch, Structure and properties of C₆₀/Pd films formed by electroreduction of C₆₀ and palladium(II) acetate trimer; evidence for the presence of palladium nanoparticles, J. Mater. Chem., 13 (2003) 518-535.
3. A. de Bettencourt-Dias, K. Winkler, W.R. Fawcett, A.L. Balch, The influence of electroactive solutes on the properties of electrochemically formed fullerene C₆₀-based films, J. Electroanal. Chem., 549 (2003) 109-117.
4. M. Płońska, A. de Bettencourt-Dias, A.L. Balch, K. Winkler, Electropolymerization of 2'-ferrocenylpyrrolidino[3',4';1,2][C₆₀]fullerene in the presence of palladium acetate. Formation of an electroactive fullerene-based film with a covalently attached redox probe, Chem. Mater., 15 (2003) 4122-4131.
5. M.E. Płońska, A. Makar, M. Wysocka, K. Winkler, De Bettencourt-Dias, A.L. Balch, Electrochemically formed two-component films of forrocenylfullero[C₆₀]pyrrolidine and transition metal complexes, Fullerenes and Nanotubes: The Building Blocks of Next Generation Nanodevices. Vol. 13, D.M. Guldi., P.V. Kamat. F.D'Souza (eds.), The Electrochemical Society, Inc., Pennington 2003, 55-64.

2002

1. A. Hayashi, A. de Bettencourt-Dias, K. Winkler, A.L. Balch, Redox-active films formed by electrochemical reduction of solutions of C₆₀ and platinum complexes, J. Mater. Chem., 12 (2002) 2116-2122.
2. M.E. Płońska, A. Dubis, K. Winkler, New insights into the electrodeposition and redox properties of [M(bipyridil)₃](ClO₄)₃ (M = Co and Fe) films in media of low dielectric constant, J. Electroanal. Chem., 526 (2002) 77-84.
3. K. Winkler, M. Wysocka, Sonoelektrochemia. Wpływ ultradźwięków na przebieg procesów elektrodowych oraz ich praktyczne wykorzystanie w elektrochemii, Wiad. Chem., 56 (2002) 895-930.

2001

1. M.E. Plonska, P. Diakowski, T.Krogulec and K.Winkler, Microelectrodes Modified with [M^III(bpy)₃](ClO₄)₃ (M=Co and Fe) as Analytical Sensors for Fullerenes in Flow Injection Analysis, Electroanalysis, 13 (2001)1185-1190.
2. M.E. Płońska, K. Winkler, Electrocatalytic processes at electrodes modified with [M^III(bpy)₃](ClO₄)₃ (M = Co and Fe), Annals of the Polish Chemical Society. Preliminary Reports Presented During Annual Meeting of the Polish Chemical Society. Katowice, September 9-13, 2001, W.W. Sułkowski (ed.), Śląskie Centrum Wydawnicze, Zabrze, 2001, p. 37.

2000

1. Winkler K., Costa D. A. and Balch A. L., Electrrochemical properties of fullerene based solid thin layers. Pol. J. Chem., 74 (2000) 1-37.
2. Winkler K., Noworyta K., Kutner W. and Balch A. L., A study of redox active C₆₀/Pd films by simultaneous cyclic voltammetry and piezoelectric microgravimetry at an electrochemical quartz crystal microbalance, J. Electrochem. Soc., 147 (2000) 2597-2603.
3. Winkler K., de Bettencourt-Dias A. and Balch A. L., Electrochemical studies of C₆₀/Pd films formed by the reduction of C₆₀ in the presence of palladium(II) acetate trimer. Effects of varying C₆₀/Pd(II) ratios in the precursor solutions, Chem. Mater., 12 (2000) 1386-1392.
4. Winkler K., McKnight N. and Fawcett W. R., Electron transfer kinetics of tris(1,10-phenanthroline)ruthenium(II) electrooxidation in aprotic solvents, J. Phys. Chem. B, 104 (2000) 5375-5380.
5. Winkler K., de Bettencourt-Dias A., Balch A. L., Kutner W. and Noworyta K., Recent advancess in the electrochemistry of fullerene/transition metal co-polymers, in Fullerenes 2000. Electrochemistry and Photochemistry, Vol. 8, S. Fukuzami, F.D’Souza i D.M. Guldi (eds.), The Electrochemical Society, Inc., Pennington 2000, 31-42.
6. Winkler K., Noworyta K., Kutner W. and Balch A. L., A study of redox active C₆₀/Pd films by simultaneous cyclic voltammetry and piezoelectric microgravimetry at an electrochemical quartz crystal microbalance, J. Electrochem. Soc., 147 (2000) 2597-2603.
7. Winkler K., de Bettencourt-Dias A. and Balch A. L., Electrochemical studies of C₆₀/Pd films formed by the reduction of C₆₀ in the presence of palladium(II) acetate trimer. Effects of varying C₆₀/Pd(II) ratios in the precursor solutions, Chem. Mater., 12 (2000) 1386-1392.
8. Winkler K., McKnight N. and Fawcett W. R., Electron transfer kinetics of tris(1,10-phenanthroline)ruthenium(II) electrooxidation in aprotic solvents, J. Phys. Chem. B, 104 (2000) 5375-5380.
9. J. Magnuszewska, T.Krogulec and A.S.Baranski, Fast Fourier Transform Square-Wave Voltammetry Detection of Phenothiazines in Capillary Electrophoresis, Chemia Analityczna (Warsaw), 45(2000)189-203.
10. K. Winkler, K. Noworyta, W. Kutner, A.L. Balch, Electrochemical quartz crystal microbalance study of redox active C₆₀/Pd polymer films, Electronic Properties of Novel Materials - Molecular Nanostructures, H. Kuzmany J. Fink, M. Mehring i S. Roth (eds.) America Institute of Physics, Melville 2000, pp. 67-70.

1999

1. Basa A., Krogulec T. and Baranski A. S.. Kinetics of sulfide ion adsorption at copper amalgam electrodes, J. Electroanal. Chem., 463 (1999) 200-211.
2. de Bettencourt-Dias A., Winkler K., Hayashi A. and Balch A. L., Electrochemical properties of MC₆₀ (M = Pd, Pt) covered electrode, in Fullerenes: Recent Advances in the Chemistry and Physics of Fullerenes and Related Materials, Vol. 7, P.V. Kamat, D.M. Guldi i K.M. Kadish (eds.), The Electrochemical Society, Inc., Pennington 1999, 47-58.
3. Poblet J. M., Munoz J., Winkler K., Concilla M., Hayashi A., Lebrilla C. B. and Balch A. L., Geometric and electronic structure of metal-cage fullerenes, C₅₉M (M = Pt, Ir) obtained by laser ablation of electrochemically deposited films, J. Chem. Soc. Chem. Commun., (1999) 493-494.
4. Winkler K., Elektrochemiczne właściwości fulerenów i ich pochodnych w roztworach, Wiad. Chem., 53 (1999) 479-528.
5. Winkler K. and Płońska M. E., Elektrochemiczne własności stałych warstw z udziałem fulerenów, Wiad. Chem., 53 (1999) 823-870.
6. Winkler K., de Bettencourt-Dias A. and Balch A. L., Charging processes in electroactive C₆₀/Pd films: effect of solvent and supporting electrolyte, Chem. Mater., 11 (1999) 2265-2273.

1998

1. Balch A. L., Costa D. A. and Winkler K.. Formation of redox-active, two-component films by electrochemical reduction of C₆₀ and transition metal complexes, J. Am. Chem. Soc., 120 (1998)9614-9620.
2. Baranski A. S., Krogulec T., Nelson L. J.and Norouzi P.. The high frequency impedance spectroscopy of Pt ultramicroelectrodes in flowing solutions, Anal. Chem., 70 (1998) 2895-2901.
3. Koerner R. , Olmstead M. M., Ozarowski A., Phillips S. L., Van Calcar P. M., Winkler K. and Balch A. L., Possible intermediates in biological metalloporphyrin oxidative degradation. Nickel, copper and cobalt complexes of ctaethylformybiliverdin and their conversion to a verdoveme, J. Am. Chem. Soc., 120 (1998) 1274-1284.
4. Koerner R., Olmstead M. M., Van Calcar P. M., Winkler K. and Balch A. L., Carbon monoxide production during the oxygenation of cobalt complexes of linear tetrapyrroles. Formation and characterization of Co(II) (tetraethylpropentdyopent anion)₂, Inorg. Chem., 37 (1998) 982-988
5. Baranski A. S. and Winkler K., The ac-voltammetric study of fast charge transfer processes in benzene solutions, J. Electroanal. Chem., 453 (1998) 29-38
6. Winkler K., New insights into the solvent effect on the oxidation kinetics of nickeloocene, Monat. Chem., 129 (1988) 1119-1132.
7. Winkler K., Mojsa R., Costa D. A. and Balch A. L., A study of C₆₀ redox processes in thin layers of organic solvets covering hanging mercury drop electrode, in Fullerenes: Recent Advances in the Chemistry and Physics of Fullerenes and Related Materials, Vol. 6, K.M. Kadish i R.S. Ruoff (eds.), The Electrochemical Society, Inc., Pennington 1998, pp. 1235-1246.
8. Balch A. L., Costa D. A. and Winkler K., Formation of redox active two component films be electrochemical co-reduction of C₆₀ and transition metal complexes, J. Am. Chem. Soc., 120 (1998) 9614-9620.
9. Winkler K. , Costa A. A., Balch A. L. and Fawcett R. W., The electroreduction of C₆₀ films in solutions containing crown ether complexes of alkali metal cations, J. Electroanal. Chem., 456 (1988) 229-237.
10. Winkler K., Costa D. A., Hayashi A. and Balch A. L., Electrode modification from the electrolysis of [M(bipyridine)₃](ClO₄)₂ (M = Co^II, Fe^II and Ru^II) in media of low dielectric constant. Electrocatalytic behavior and an amperometric C₆₀ sensor, J. Phys. Chem. B, 102 (1998) 9640-9646.
11. Winkler K., Mojsa R., Costa D. A. and Balch A. L., Electrode processes in thin layers of organic solvents covering hanging mercury drop electrode. Effect on metal ion and fullerene (C₆₀) reduction, Anal. Chem., 70 (1998) 5244-5251.

1997

1. Winkler K., Costa D. A., Balch A. L. and Fawcett W. R., Alteration of the electrochemistry of fullerene C₆₀ in the presence of dioxygen. Formation of a redox active polymeric film, Adv. Mat., 9 (1997) 153-156.
2. Winkler K., Costa D. A., Balch A. L. and Fawcett W. R., Redox catalysis in electropolymerized fullerene films formed from C₆₀ and dioxygen, in: Fullerenes: Recent Advances in the Chemistry and Physics of Fullerenes and Related Materials, Vol. 5, K. M. Kadish i R. S. Ruoff (eds.), The Electrochemical Society, Inc., Pennington, 1997, 44-53.
3. Winkler K., Szulborska A., Kozlowski J. and Krogulec T., The electrode processes of Ru(III) thiocyanate complexes at mercury and platinum electrodes, J. Electroanal. Chem., 435 (1997) 267-271.
4. Attar S., Balch A. L., Van Calcar P. M. and Winkler K., Electron transfer behavior and solid state structures of the helical cobalt complexes of the open-chain tetrapyrrole ligand, octaethyl-bilindione J. Am. Chem. Soc., 119 (1997) 3317-3323.
5. Attar S., Ozarowski A., Van Calcar P. M., Winkler K. and Balch A. L., Axial ligation modulates the electron distribution in helical cobalt complexes derived from octaethylbilindione, J. Chem. Soc., Chem. Commun., (1997) 1115-1116.
6. K. Winkler, D.A. Costa, A.L. Balch and W.R. Fawcett, Alteration of the electrochemistry of fullerene C₆₀ in the presence of dioxygen. Formation of a redox active polymeric film, Adv. Mat., 9 (1997) 153-156.
7. Balch A. L., Costa D. A., Fawcett W. R. and Winkler K., The solvent effect on the electrochemical behaviour of C₆₀ layer in the presence of alkali-metal cations, J. Electroanal. Chem., 427 (1997) 137-146.
8. Balch A. L., Catalano V. J., Costa D. A., Fawcett W. R., Fedurco M., Ginwalla A. S., Olmstead M. M., Noll B. C. and Winkler K., Transition metal fullerene chemistry. The route from structural studies of exohedral adducts to the formation of redox active films, J. Phys. Chem. Solids, 58 (1997) 1633-1643.

1996

1. Balch A. L., Costa D. A., Fawcett W. R. and Winkler K., Electronic communication in fullerene dimers. Electrochemical and electron paramagnetic resonance study of the reduction of C₁₂₀O, J. Phys. Chem., 100 (1996) 4823-4827.
2. Winkler K., Baranski A. S and Fawcett W. R., Solvent effects in simple electron transfer reactions, J. Chem. Soc., Faraday Trans., 92 (1996) 3899-3904.

1995

1. Krogulec T., The electrode processes of copper in cyanate, thiocyanate, selenocyanate and thiourea solutions at mercury and copper amalgam electrodes. Part II: Selenocyanate Solution, Pol. J. Chem., 69 (1995) 746-755.
2. Winkler K. and Krogulec T., The study of electrode processes of Fe(II)-thiosulphate complexes on mercury electrodes, J. Electroanal. Chem., 386 (1995) 127-134.
3. Winkler K. and Mojsa R., On the formation and oxidation of a heterogeneous amalgam of iron at ultramicroelectrodes, Pol. J. Chem., 69 (1995) 731-741.
4. Winkler K., The kinetics of electron transfer in Fe(CN)₆^4-/3- redox system on platinum standard-size and ultramicroelectrodes, J. Electroanal. Chem., 388 (1995) 151-159.
5. Winkler K., Costa D. A., Balch A. L. and Fawcett W. R. , A study of fullerene epoxide electroreduction and electropolymerization processes, J. Phys. Chem., 99 (1995) 17431-17436.
6. Balch A. L., Cullison B., Fawcett W. R., Ginwalla A. S., Olmstead M. and Winkler K., Structural and electrochemical characterization of the products of the C₆₀-piperazine reaction. J. Chem. Soc., Chem. Commun., (1995) 2287-2288.